Even though this article is about adding a new user in Kubuntu, it's generally the same with any Linux distribution using KDE as their desktop environment. This article is specific to KDE version 4.
This article discus adding user using the graphical user interface in Kubuntu / KDE. For command line option or to add user in Ubuntu/Gnome, refer to the following articles;
From the K Menu, which is usually located on the lower left of the screen, go to the Computer tab and click on the System Settings link
On the System Settings window, open the User Management window by clicking on the icon under the System Administration category
You can now start entering user details such as the login name and the full name. The rest of the fields are automatically set
Select the Privileges and Groups tab and you can optionally set groups you want the user to belong to, or you can just leave it to the default values
Select the Password/Security tab enter the password for the user. You can also set the password expiration date etcetera if you know what you're doing